Phase-Transformation-Activated MnCO3 as Cathode Material of Aqueous Zinc-Ion Batteries
نویسندگان
چکیده
The intrinsic high safety of rechargeable aqueous batteries makes them particularly advantageous in the field large-scale energy storage. Among them, Zn–Mn with density, low cost, discharge voltage, and nontoxicity have been considered as one most promising battery systems. However, exiting research on manganese-based cathode materials mainly focuses diverse manganese oxides analogs, while reports other analogs performance are still limited. Herein, we report a MnCO3 material, which can be manufactured large scale by facile coprecipitation method. Interestingly, spontaneously converted into MnO2 material during charging process. Zn–MnCO3 delivers highly specific capacity (280 mAh g?1) even at current density 50 mA g?1. It is also noteworthy that loading mass (7.2 mg cm?2) exhibits good reversibility charge–discharge for 2000 cycles, showing competitive cycling stability
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ژورنال
عنوان ژورنال: Batteries
سال: 2022
ISSN: ['2313-0105']
DOI: https://doi.org/10.3390/batteries8110239